I seem to remember as a young child being told that it is safe to touch a Van de Graff generator (for the hair demonstration), but that if you let go before it is safe you will get a nasty shock. I know a bit more about electricity now, and I’m a little skeptical now. Is it possible to get a shock from letting go of something?
If you’re in some kind of science experiment where you’re being conditioned to not stop touching something: Yes.